西北农林科技大学：《有机化学 Organic chemistry》课程教学课件（2010）Chapter 01 Introduction（主讲：王俊儒）

0 样华院 张继文博士 袁茂森博士 数的可Instant Notes 同 有机化学 Sith Editon Organic Chemistry 有机化学 “点（第6版） 出他L四 C.Patrick

张继文博士 袁茂森博士

0际人号 主要参考书 Text book:Organic Chemistry,6th Edition L.G.Wade,Jr. Instant notes in organic chemistry,by GL Patrick ■有机化学，付建熙主编，高教出版社 ■有机化学学习指导，朱玮等主编，高教出版社 ■邢其毅基础有机化学” ■有机化学资料： ●校http:/210.27.80.892004 youhua⊥ http://210.27.80.165/jingpin/2004/youhua/index.htm MIT http://www.core.org.cn/OcwWeb/Chemistry/5-130rganic- Chemistry-IISpring2003/CourseHome/index.htm ●科学网 http://www.sciencenet.cn/bbs/showforum.aspx?forumid=87

主要参考书 „Text book: Organic Chemistry, 6th Edition L. G. Wade, Jr. „Instant notes in organic chemistry, by GL Patrick „有机化学，付建熙主编，高教出版社 „有机化学学习指导，朱玮等主编，高教出版社 „邢其毅“基础有机化学” „有机化学资料: z校http://210.27.80.89/2004/youhua/ zhttp://210.27.80.165/jingpin/2004/youhua/index.htm zMIT http://www.core.org.cn/OcwWeb/Chemistry/5-13Organic￾Chemistry-IISpring2003/CourseHome/index.htm z科学网 http://www.sciencenet.cn/bbs/showforum.aspx?forumid=87

0 CONTENT 样华院 1 Introduction and Preview 2 Structure and Properties of Organic Molecules 3 Brief Introduction and Nomenclature of O.Ms 4 Structure and Stereochemistry of Alkanes 5 The Study of Chemical Reactions 6 Stereochemistry:Chirality ■7 Alkyl Halides 8 Structure and Synthesis of Alkenes ■10 Alkynes 11 Conjugated Systems and Orbital Symmetry Review &Discussion 1:Hydrocarbons and new applications 14 Structure and Synthesis of Alcohols 15 Reaction of Alcohols

CONTENT „1 Introduction and Preview „2 Structure and Properties of Organic Molecules „3 Brief Introduction and Nomenclature of O.Ms „4 Structure and Stereochemistry of Alkanes „5 The Study of Chemical Reactions „6 Stereochemistry: Chirality „7 Alkyl Halides „8 Structure and Synthesis of Alkenes „10 Alkynes „11 Conjugated Systems and Orbital Symmetry „Review &Discussion 1: Hydrocarbons and new applications „14 Structure and Synthesis of Alcohols „15 Reaction of Alcohols

0际人号 CONTENT 16 Ethers,Epoxides and Sulfides(SELF-STUDY) 17 Aromatic Compounds 18 Reactions of Aromatic Compounds 19 Ketones and Aldehydes Review Discussion 2:O.Ms Containing Oxygen ■20 Amines ■21 Carboxylic Acids 22 Carboxylic Acid Derivatives 23 Condensation and Alpha Substitution of Carbonyl Compounds Special topics:24 Carbohydrates and Nucleic Acides. Special topics:25 Amino Acides,Peptides and Proteins. Special topics:26 Lipids. Review Discussion 3:Biological molecules in life

CONTENT „16 Ethers, Epoxides and Sulfides(SELF-STUDY) „17 Aromatic Compounds „18 Reactions of Aromatic Compounds „19 Ketones and Aldehydes „Review & Discussion 2: O.Ms Containing Oxygen „20 Amines „21 Carboxylic Acids „22 Carboxylic Acid Derivatives „23 Condensation and Alpha Substitution of Carbonyl Compounds „Special topics: 24 Carbohydrates and Nucleic Acides. „Special topics: 25 Amino Acides, Peptides and Proteins. „Special topics: 26 Lipids. „Review & Discussion 3: Biological molecules in life

0 样华院。 ■DURATION:64h ■SCORE(%) ●NORMAL WORK(20/O) >HOMEWORK >DISCUSSION OUNIT TEST MIDTERM TEST(40%) ●FINAL TEST(40/O)

„DURATION: 64h „SCORE（%） zNORMAL WORK(20%) ¾HOMEWORK ¾DISCUSSION zUNIT TEST & MIDTERM TEST(40%) zFINAL TEST(40%)

Q:what is petrolum ether? ■Ethers？Alkanes?Alkenes? ●石油醚是哪类化合物？醚？烷烃？烯烃？ A volatile fraction of petroleum consisting chiefly of pentanes and hexanes. The term "petroleum ether"is an old term used to refer to a mixture of hydrocarbons with a specific boiling point range.In other words, there is no ether in petroleum ether! Synonyms for petrolem ether include onaphtha,petroleum benzin,benzin,ligroin,white spirit,and the lab slang,"pet ether

Q: what is petrolum ether? „Ethers ? Alkanes? Alkenes? z石油醚是哪类化合物? 醚? 烷烃? 烯烃 ? „A volatile fraction of petroleum consisting chiefly of pentanes and hexanes. „The term "petroleum ether" is an old term used to refer to a mixture of hydrocarbons with a specific boiling point range. In other words, there is no ether in petroleum ether! „Synonyms for petrolem ether include znaphtha, petroleum benzin, benzin, ligroin, white spirit, and the lab slang, "pet ether

0林期 Q:what is petrolum ether? Petroleum ether is obtained from petroleum refineries as the portion of the distillate which is intermediate between the lighter naphtha and the heavier kerosene.(movie) specific gravity of between 0.6 and 0.8 ■Remember .Petroleum ether should not be confused with the class of organic compounds called ethers,which contain the -0-functional group. Likewise,benzine should not be confused with benzene.Benzine is a mixture of alkanes,e.g., pentane,hexane,and heptane,whereas benzene is a cyclic,aromatic hydrocarbon,C6H6

Q: what is petrolum ether? „Petroleum ether is obtained from petroleum refineries as the portion of the distillate which is intermediate between the lighter naphtha and the heavier kerosene. （movie ） „specific gravity of between 0.6 and 0.8 „Remember zPetroleum ether should not be confused with the class of organic compounds called ethers, which contain the -O￾functional group. zLikewise, benzine should not be confused with benzene. Benzine is a mixture of alkanes, e.g., pentane, hexane, and heptane, whereas benzene is a cyclic, aromatic hydrocarbon, C 6 H 6

08 Study Tips提示 Read the assigned textbook chapter before class. Write out the main notes and focus on what covered in class. Spend at least two to three hours studying out of class for every time spent in class. .This is a very minimal amount of time to spend on a course of this type.You will be rewarded for your efforts.Remember that you are competing with other students.Students that fail usually do so because they're too busy not because they're dumb or lazy. ■Be an active learner Form a study group and be an active learner.Don't just memorize,but integrate the information into your existing knowledge base and emphasize understanding. ■提前预习/做课堂笔记/课后做一定量的题/勤思考，多交流，及 时整理 “Chance favors the prepared mind.” ■答疑时间： ----Louis Pasteur

Study Tips 提示 „Read the assigned textbook chapter before class. „Write out the main notes and focus on what covered in class. „Spend at least two to three hours studying out of class for every time spent in class. zThis i s a very minimal amount of time to spend on a course of this type. You will be rewarde d for your efforts. Remember that you are competing with other students. Students that fail usually do so because they're too busy not because they're dumb or lazy. „Be an active learner zForm a study group and be an active learner. Don't just mem orize, but integrate the information into your existing knowl edge base and emphasize understanding. „提前预习 /做课堂笔记 /课后做一定量的题 /勤思考 ,多交流 , 及 时整理 „答疑时间： “Chance favors the prepared mind.” ----Louis Pasteur

0标4号 样华院 Organic Chemistry,6th Edition L.G.Wade,Jr. Chapter 1 Introduction and Review By Junru Wang Email:wangjr07@163.com

By Junru Wang Email: wangjr07@163.com Organic Chemistry, 6th Edition L. G. Wade, Jr. Chapter 1 Introduction and Review

0标g Key Notes 样华院 ■Definitions ■Atomic Structure Electronic Structure Electronic Configurations ●Bond Formation ●Covalent Bonds ■Lewis Structures ■Resonance ■Acids and Bases Arrhenius Acids and Bases BrOnsted-Lowry Acids and Bases ●Lewis Acids and Bases

Key Notes „Definitions „Atomic Structure zElectronic Structure zElectronic Configurations zBond Formation zCovalent Bonds „Lewis Structures „Resonance „Acids and Bases zArrhenius Acids and Bases zBrØnsted-Lowry Acids and Bases zLewis Acids and Bases