上海交通大学：《大学化学》教学资源_试卷与答案_2006-2007学年第一学期“大学化学（J类）”理论课样卷与答案

Chem-130 Final Exam 2006/2007 Winter (Part questions of final Exam) Part. dp中r 时04→0D2日 1104 )4倒·3D2细一20影国 010mh3 aw Part II Hg+3O,(g-B,O的+3H,O0△F=21475 of 0星 2POCl(p)2PClig)+o:(g) A=572 kImol As 179 JmalK Co,(Clo,()+clo+(Ep [COM [OHRate) (A)O mnd (B)CIO? 123 0.0248 g.Which commplexfes)(a)to (e)has bave a color (ie.neither white no colorlessy?Pleas derlire it them (亿NHCL Na[(e)[F H-oulCh h.Whch of the following compleses are bigh-spn sd which coes ae low-spin?Wnte H or L betind them IcH(co%]L (b)[CrClHo)1HeKf产H(④KPEL Answer PartI 0.03MN0-2N0:fal0.023L2*0064MN02Knr-.012s0236-,060 Opicalis Freezing point,40g KC1400:40.g(74..40kg*1.8C/m0.45 PartII b.Solution AC=A-298KA=+519 kmol cal.eenPClsmigpm hebTg I may be qute inac rt.[OH x=hgt009nn030L1g0m828000270=10c=T☐ d.( gDLe甲ONa,e g.b).c) h.([Cco)L ([crCl/t:o)]F (K:PF L (a:CO is strong ligand,d:Pt is heavy metal)All complexes are octahedral 1.Am0 or introduction of a ratiomal system ofm(m kg