东莞理工学院化学生物工程系：《有机化学》卤代烃（周显宏）

NERSITY O 卤代烃课堂练习 理工 梅花(中国十大名花之一)

2021/1/21 1 卤代烃课堂练习

The Nobel Prize in Chemistry 1994 George A. Olah (1927~) for his contribution to carbocation chemistry (CH3)3CF SbFs -(CH3)3C SbFe 超酸 通过核磁共振 观察到

2021/1/21 2 George A. Olah (1927 ~ ) (CH3 ) 3CF + (CH3 ) 3C SbF6 通过核磁共振 观察到 SbF5 超酸 The Nobel Prize in Chemistry 1994 “for his contribution to carbocation chemistry

The Nobel Prize in Chemistry 1990 E.J. Corey (1928~ for his contribution to Retrosynthetic analysis

2021/1/21 3 The Nobel Prize in Chemistry 1990 “for his contribution to Retrosynthetic analysis” E. J. Corey (1928 ~ )

完成下列反应: (1)H2C Fo PC1s 理工 (ii)H2C- OH +CaHsOSO2OC2Hs (111)CH,(CH,)Br+SbF (iv)CH CH, CHBrCHx+ AgoNO C1+P(C2H5)3 202l/1/21

2021/1/21 4 完成下列反应：

CH 3 +NaCN 理工 Br CH,Br +NaCN (ⅷi)H2 +HI IX +( ch3) Culi Br 2021

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CH2 CH CHo CH, CH 31a+NH2(夜) 理工 H2C Br (x i)4CH3MgC1 sicl4 (x ii) 2CH3 CH2 CH(CH3)MgCI HgCl2 (xiii)(CH3CH2bCLi + H2O (xiv)BrCH2)4Br Nahs(lmol) NaOH (X V)(CH3h CHC(CH3)3 Br2(1mol) D2O 光 无水乙醚 202l/1/21

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()H2C H,C OCHCH 3 (ii) CH3(CH2)3F (iw) CH3CH2 CHONO p(c h3)3c1 (vi) CH CH.CN (viii) H,c ERSITY 1 202l/1/21

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(x) H3CH,C CH2CH2CH 理工 H3 H CH (xi) (CH3)4Si (xii) (CH3CH2CHhHg (xii)(CH3 CH2)3CH (x)(CH2)2C(CH2)3 202l/1/21

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NERSITY 理工 社丹(中国十大名花之一)

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