东莞理工学院化学生物工程系：《有机化学》芳烃（周显宏）

芳经课练习

21 January 2021 芳烃课堂练习 1

完成下列反应式 h2 C KMno CH AlCl t(Ch33C CI 100℃ 3.H3C CI- HNO KMno HoSO △ HNO3 HNH-C NO2 hSO (CH3)3C KMnO4 21 January 2021 2

21 January 2021 2 1. 2. 3. 4. 5. 完成下列反应式： △ C KMnO4 H3 C 2 H5 ＋ (CH3 ) 3 CCl CH3 CH3 AlCl 3 100℃ H2 SO4 △ H Cl KMnO4 3 C HNO3 H2 SO4 NH NO2 HNO3 C O △ KMnO4 (CH3 ) 3 C

6 H2SO4 AlCl 1)KMnO4/△ HCl (2)浓HNO3/H2SO4 8. CHo-CHo Alcls KMnO 加热 21 January 2021

21 January 2021 3 6. 7. 8. H2 S O 4 HN O 3 CO O

1. HOOC COOH CH COOH NO 2. 3 CH C(CH3) N〈C-NH 5.(CH3)3C2COOH 6O2N/C-O NO2 COOH NO 8 COOH 21 January 2021

21 January 2021 4 HO O C C O O H C H 3 C H 3 C ( C H 3 ) 3 N O 2 C l CH 3 N O 2 C O O H C l O 2N C NH N O2 O ( C H 3 ) 3 C C O OH O 2 N C N O 2 O O N O 2 C O O H C 2 H5 C O OH 1. 2. 3. 4. 5. 6. 7. 8