东莞理工学院：《有机化学》课堂练习_卤代烃

卤代烃课堂练习 就论票 梅花(中国十大名花之一)

2021/2/23 1 卤代烃课堂练习

The Nobel Prize in Chemistry 1994 George A. Olah (1927~) for his contribution to carbocation chemist (CH3)3CF SbFs (CH3)3C SbF6 超酸 通过核磁共振 观察到

2021/2/23 2 George A. Olah (1927 ~ ) (CH3 ) 3CF + (CH3 ) 3C SbF6 通过核磁共振 观察到 SbF5 超酸 The Nobel Prize in Chemistry 1994 “for his contribution to carbocation chemistry

The Nobel Prize in Chemistry 1990 E. J. Corey (1928 for his contribution to Retrosynthetic analysis

2021/2/23 3 The Nobel Prize in Chemistry 1990 “for his contribution to Retrosynthetic analysis” E. J. Corey (1928 ~ )

完成下列反应 1)H2 0+ Pci (1)H2C -OH CaHsOSO2OC2Hs (ill)CH (CH)Br+S]F (iv) CH, CH, CHBrCH,+ AgONO F(C2H5)3 2021/2/2

2021/2/23 4 完成下列反应：

CH 3 +ⅠIaCN Br -CH,Br +NaCN ) +HI 1X +(CH3)culi 2021 Br

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CH3 CH2 CH ChCH 3Na+H2() H2C Br (x i)4CH3MgC1 Sic14 (x ii)2CH3 CH2CH(CH3)MgCI Hgcl ×i)(CH3H2)2CLi+H2O (x iv)BrCH2)4Br NaHs(Imol) HaOH (x v)(CH3h CHC(CH3)3 Br2(lmol 光 无水乙醚 2021/2/23

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(i) H3C- (1 C OCH, CH3 3 (iii) CH3(CH2)3F (iw) CH3 CH2CHONO P(CHs2C1-(vi) (i) CHCN (wii) H3C- NERS∥P 2021/2/23 3

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H3 CH2C CH2CH2CH3 H CH3 (xi)(CH3)4Si (xii)(CH3 CH,CHhH g (xiii)(CH3 CH2)3 CH (x)(CH32C(CH2)3 2021/2/23

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NINERSITY 社丹(中国十大名花之一)

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