东莞理工学院：《有机化学》课堂练习_芳烃

劳经课掌练习

23 February 2021 芳烃课堂练习 1

完成下列反应式 HC CH KMnO4 △ AlCl 2. +(CH3)3CCI 100℃ CH3 3.H3C√ clinO KMnO H2SO4 HNO 4 SNH-C ANO2 H2SO4 .(CH3)3C KMnO4 △ 23 February 2021 2

23 February 2021 2 1. 2. 3. 4. 5. 完成下列反应式： △ C KMnO4 H3 C 2 H5 ＋ (CH3 ) 3 CCl CH3 CH3 AlCl 3 100℃ H2 SO4 △ H Cl KMnO4 3 C HNO3 H2 SO4 NH NO2 HNO3 C O △ KMnO4 (CH3 ) 3 C

6 HNO O-C H2SO4 AlCl ①)KMQ4△ HCl (2)浓HNO3/H2SO4 8. AlCl KMnO t CHoCHo 加热 23 February 2021

23 February 2021 3 6. 7. 8. H2 SO4 HNO3 C O O

1.HOOC- COOH CH CH COOH NO NO 2 3 C(CH3)3 4 C-NH〈NO 5.(cH3)c〈》CooH6.02N 入NO OOH 7 8 > COOH 23 February 2021

23 February 2021 4 HO O C C O O H C H 3 C H 3 C ( C H 3 ) 3 N O 2 C l CH 3 N O 2 C O O H C l O 2N C NH N O2 O ( C H 3 ) 3 C C O OH O 2 N C N O 2 O O N O 2 C O O H C 2 H5 C O OH 1. 2. 3. 4. 5. 6. 7. 8