中国海洋大学：《无机化学 Concise Inorganic Chemistry》课程教学资源（PPT课件，英文）Chapter 11 Elements in p Block

Chapter 11 Elementsin p-Block1Introduction2Halogens3Oxygenandchalcogens4Nitrogen,phosphorus,arsenic,antimony,bismuth5Carbon,silicon,germanium,tin,lead6 Boron,aluminum,thallium7 Hydrogenand noble gases8Summary

1 Chapter 11 Elements in p - Block 1 Introduction 2 Halogens 3 Oxygen and chalcogens 4 Nitrogen, phosphorus, arsenic, antimony, bismuth 5 Carbon, silicon, germanium, tin, lead 6 Boron, aluminum, thallium 7 Hydrogen and noble gases 8 Summary

1 Introduction1-2 Characteristics of elements in p- BlockHHeFBNNe0CSSiPArAlCI?BrGaAsSeGeXeTeSnSb1InTIBiPbPoAtRn

2 1 Introduction 1-2 Characteristics of elements in p- Block H He B C N O F Ne Al Si P S Cl Ar Ga Ge As Se Br Kr In Sn Sb Te I Xe Tl Pb Bi Po At Rn

outer electron configurations : ns?npl-6O group: ns?np6With their closed-shell electron configurations ns?np,thenoblegas elements of Ogroupneitherattractnorloseelectronsundercommonconditions.VIA-IIIA: ns?npl-5numberofvalenceelectronsthe highest oxidation number=groupnumberThe 2l nonmetalelements, each tends to attract electronsto itself to reach the closed-shell electron configurations

3 outer electron configurations ：ns2np1-6 0 group：ns2np6 With their closed-shell electron configurations ns2np6 , the noble gas elements of 0 group neither attract nor lose electrons under common conditions. ⅦA-IIIA：ns2np1－5 number of valence electrons = the highest oxidation number = group number The 21 nonmetal elements, each tends to attract electrons to itself to reach the closed-shell electron configurations

1-2 Trends of atomic propertiesFrom top to bottom in the same group,rincreases, Ii, Ei and X decrease

4 1-2 Trends of atomic properties From top to bottom in the same group, r increases, I 1, E1 and X decrease

Abnormality for elements in period 2highelectronegativityvalue(X),smallradius,no d orbitalforuseTheelectronaffinityE,:FBr>IX-Xbondstrengths:FBr>ICoordinationnumber CN≤4

5 Abnormality for elements in period 2 high electronegativity value (X) , small radius, no d orbital for use. The electron affinity E1 : F Br > I X-X bond strengths: F Br > I Coordination number CN ≤ 4

Similarity of elements in periods 5 and 6镧系收缩:s-La to zLu ， the radius of Lu isonly 0.11A°less than that of LaLanthanide contraction causes the radii ofelements of period 6 almost equal to thoseof elements in the same group of period 5

6 Similarity of elements in periods 5 and 6 镧系收缩:57La to 71Lu ，the radius of Lu is only 0.11Aºless than that of La Lanthanide contraction causes the radii of elements of period 6 almost equal to those of elements in the same group of period 5

中间排异样性Elements in period 4 having 3d10Compared with elements in periods 2 and 3the effective nuclear charge (Z*) increaseand the radius decrease, which causebiggerZ*/rvalueand biggerelectronegativityvalue

7 中间排异样性 Elements in period 4 having 3d10 Compared with elements in periods 2 and 3, the effective nuclear charge (Z*) increase and the radius decrease，which cause bigger Z*/r value and bigger electronegativity value

2 Halogens2-1 General properties2-2 Elements2-2-1 Properties2-2-2 Preparations (制备)2-2-3 Usages2-3 Compounds2-3-1 HX2-3-2 HalidesInterhalogencompounds（卤素间化合物）Polyhalogen compounds(多卤化物)2-3-3 Oxides (OF2, CIO2, I,Os)2-3-4Oxiacids（含氧酸）/salts

8 2 Halogens 2-1 General properties 2-2 Elements 2-2-1 Properties 2-2-2 Preparations (制备) 2-2-3 Usages 2-3 Compounds 2-3-1 HX 2-3-2 Halides Interhalogen compounds (卤素间化合物) Polyhalogen compounds(多卤化物) 2-3-3 Oxides (OF2 , ClO2 , I2O5 ) 2-3-4 Oxiacids (含氧酸) /salts

2-1 General propertiesOuter electron configuration: ns?np5Oxidation numbersionic bond, NaFcovalent bond, HFcoordination bond, BF4、 AgCl+1， +3， +5， +7when halogen element combine with moreelectronegative elements, such as CiO andpolyhalogen compounds

9 2-1 General properties ◼ Outer electron configuration：ns2np5 ◼ Oxidation numbers -1 ionic bond, NaF covalent bond, HF coordination bond, BF4 －、AgCl2 － +1，+3，+5，+7 when halogen element combine with more electronegative elements, such as ClO2 and polyhalogen compounds

Existing form in nature: X-, MXFrom F to I, r increase,while I、 E,、 XdecreaseWith an exception: Eic> EiF10

10 ◼ Existing form in nature：X－, MXn ◼ From F to I, r increase， while I1、E1、X decrease With an exception：E1Cl > E1F