厦门大学化学化工学院：《有机化学》课程教学资源（课件讲稿，双语版）第十四章 芳香化合物（14.8-14.11）

ORGANIC CHEMISTRY Chapter 14 14.8 Other Aromatic Compounds Department of Chemistry, Xiamen University

ORGANIC CHEMISTRY Department of Chemistry, Xiamen University Chapter 14 14.8 Other Aromatic Compounds

ORGANIC CHEMISTRY Chapter 14 14.8A Benzenoid Aromatic Compounds Naphthalene Anthracene Phenanthrene 菲 Py rene Benzola pyrene 芘 苯并芘 Department of Chemistry, Xiamen University

ORGANIC CHEMISTRY Department of Chemistry, Xiamen University Chapter 14 14.8A Benzenoid Aromatic Compounds Naphthalene Anthracene Phenanthrene Pyrene Benzo[α]pyrene 萘 蒽 菲 芘 苯并芘

ORGANIC CHEMISTRY Chapter 14 14.8B Nonbenzenoid aromatic Compounds + Azulene 萸 Department of Chemistry, Xiamen University

ORGANIC CHEMISTRY Department of Chemistry, Xiamen University Chapter 14 14.8B Nonbenzenoid Aromatic Compounds Azulene 薁

ORGANIC CHEMISTRY Chapter 14 148 Fullerenes 足球烯 Department of Chemistry, Xiamen University

ORGANIC CHEMISTRY Department of Chemistry, Xiamen University Chapter 14 14.8C Fullerenes

ORGANIC CHEMISTRY Chapter 14 14.9 Heterocyclic Aromatic Compounds Department of Chemistry, Xiamen University

ORGANIC CHEMISTRY Department of Chemistry, Xiamen University Chapter 14 14.9 Heterocyclic Aromatic Compounds

ORGANIC CHEMISTRY Chapter 14 o a ring that contains at least one heteroatom(an atom other than carbon) is called a heterocycle and a substance based on a heterocyclic ring is a heterocyclic compound o Heterocyclic compounds containing n. o or s are by far the most common H Pyridine Pyrrole F uran Thiophene 吡啶 吡咯 呋喃 噻吩 Department of Chemistry, Xiamen University

ORGANIC CHEMISTRY Department of Chemistry, Xiamen University Chapter 14 A ring that contains at least one heteroatom (an atom other than carbon) is called a heterocycle, and a substance based on a heterocyclic ring is a heterocyclic compound. Heterocyclic compounds containing N, O or S are by far the most common. N NH O S Pyridine Pyrrole Furan Thiophene 吡啶 吡咯 呋喃 噻吩

ORGANIC CHEMISTRY Chapter 14 14.10 Aromatic Compounds in Biochemistry Department of Chemistry, Xiamen University

ORGANIC CHEMISTRY Department of Chemistry, Xiamen University Chapter 14 14.10 Aromatic Compounds in Biochemistry

ORGANIC CHEMISTRY Chapter 14 o Three amino acids necessary for protein synthesis contain an aromatic ring CHCHCO2 CH CHCO2 HO CH,CHCO? NH3 NH +NH3 H Phenylalanine苯丙氨酸 Tyrosine酪氨酸 Tryptophan色氨酸 o Derivatives of purine and pyrimidine are essential parts of dna and rna N N NNH Purine嘌呤 Pyrimidine嘧啶 Department of Chemistry, Xiamen University

ORGANIC CHEMISTRY Department of Chemistry, Xiamen University Chapter 14 Three amino acids necessary for protein synthesis contain an aromatic ring: CH2CHCO2 NH3 CH2CHCO2 NH3 HO Phenylalanine Tyrosine N H CH2CHCO2 NH3 苯丙氨酸 酪氨酸 Tryptophan 色氨酸 Derivatives of purine and pyrimidine are essential parts of DNA and RNA. N N N N H N N Purine 嘌呤 Pyrimidine 嘧啶

ORGANIC CHEMISTRY Chapter 14 o Many aromatic compounds are hazardous. Many are quite toxic, and several benzeniod compounds including benzene itself are carcinogenic CH Benzola]pyrene 7-Methylbenz[a]anthracene 苯并芘 7-甲基苯并蒽 Department of Chemistry, Xiamen University

ORGANIC CHEMISTRY Department of Chemistry, Xiamen University Chapter 14 Many aromatic compounds are hazardous. Many are quite toxic, and several benzeniod compounds, including benzene itself, are carcinogenic. Benzo[α]pyrene 苯并芘 CH3 7-Methylbenz[α]anthracene 7-甲基苯并蒽

ORGANIC CHEMISTRY Chapter 14 14.11 Spectroscopy of Aromatic Compounds Department of Chemistry, Xiamen University

ORGANIC CHEMISTRY Department of Chemistry, Xiamen University Chapter 14 14.11 Spectroscopy of Aromatic Compounds