浙江科技大学：《物理化学》课程教学资源（教学大纲）物理化学教学大纲（2005）Physical Chemistry（A）

Physical Chemistry (A)Syllabus of Zhejiang University of Science and TechnologyPhysical Chemistry (A)S/N:10421100-10421110Classification: Specialized basic courseApplicable to: Chemical Engineering and TechnicsMaterials Science and EngineeringPharmaceutical EngineeringTotal Hours:102Credit Points: 6Requirements on foundation courses: Advanced MathematicsGeneralPhysicsInorganicandAnalyticalChemistryOrganic ChemistryWritten by: Zhang LiqingA. Characteristics and StatusPhysical chemistry is engaged in the research of basic principles of chemical changes,phase changes and physical changes concerned, mainly including the rules ofequilibrium and change speed. As a specialized basic course for chemical engineeringand technics, materials science and engineering, pharmaceutical engineering majors,etc, physical chemistry is not only an important part for cultivating integralknowledge structure and capability structure of engineering and technical talents ofthe said majors, but also a foundation for the subsequent specialized courses.B. Teaching Targets1. After studying this course, students shall master basic theoretical knowledgewell, understand important concepts and basic principles, and master basiccomputational technique of physical chemistry.2. After studying this course, students shall master theoretical researchapproaches of physical chemistry, especially the thermodynamics approaches, andunderstand methods of statistical thermodynamics basically.3. After studying this course, students shall receive the training of generalscientific approaches further and improve the ability of analyzing and resolvingproblems of physical chemistry. Training of scientific approaches shall be carried outthrough thecourseof teaching,therefore,particularlythroughlearningofthermodynamics and dynamics, students will master general methods of inducing anddeducing from experimental results, be familiar with methods of concluding theoriesfrom hypothesis and master general scientific approaches of resolving practicalproblems through theories and according to real conditions.C.Teaching Contents, Basic Requirements and Time Allocation

Syllabus of Zhejiang University of Science and Technology Physical Chemistry (A) Physical Chemistry (A) S/N: 10421100-10421110 Classification: Specialized basic course Applicable to: Chemical Engineering and Technics Materials Science and Engineering Pharmaceutical Engineering Total Hours: 102 Credit Points: 6 Requirements on foundation courses: Advanced Mathematics General Physics Inorganic and Analytical Chemistry Organic Chemistry Written by: Zhang Liqing A. Characteristics and Status Physical chemistry is engaged in the research of basic principles of chemical changes, phase changes and physical changes concerned, mainly including the rules of equilibrium and change speed. As a specialized basic course for chemical engineering and technics, materials science and engineering, pharmaceutical engineering majors, etc, physical chemistry is not only an important part for cultivating integral knowledge structure and capability structure of engineering and technical talents of the said majors, but also a foundation for the subsequent specialized courses. B. Teaching Targets 1. After studying this course, students shall master basic theoretical knowledge well, understand important concepts and basic principles, and master basic computational technique of physical chemistry. 2. After studying this course, students shall master theoretical research approaches of physical chemistry, especially the thermodynamics approaches, and understand methods of statistical thermodynamics basically. 3. After studying this course, students shall receive the training of general scientific approaches further and improve the ability of analyzing and resolving problems of physical chemistry. Training of scientific approaches shall be carried out through the course of teaching; therefore, particularly through learning of thermodynamics and dynamics, students will master general methods of inducing and deducing from experimental results, be familiar with methods of concluding theories from hypothesis and master general scientific approaches of resolving practical problems through theories and according to real conditions. C. Teaching Contents, Basic Requirements and Time Allocation

Physical Chemistry (A)Syllabus of Zhejiang University of Science and TechnologyIntroductionTo find out research contents of physical chemistry, understand researchapproaches and the development trend and characteristics of modern physicalchemistry,and master the learning approaches for the course of physical chemistry.Major Contents:0.1 Research contents of physical chemistry0.2Researchapproachesofphysicalchemistry0.3 Establishment and development of physical chemistry0.4 Development trend and characteristics of modern physical chemistry0.5 Learning approaches for the course of physical chemistryKey Points:1. Intentions and contents of physical chemistry2. Research approaches of physical chemistry3. Learning approaches for the course of physical chemistryNodus:1.Researchapproachesof physical chemistry2. Learning approaches for the course of physical chemistryChapter 1 PVT property of gasTo master the perfect gas equation and mode, Dalton law and Amagat law,comprehend the liquefaction and critical properties ofreal gas,master perfect gasmode and its theoretical explanation, comprehend the principle of correspondingstatediagram ofcompressibilityfactor and related calculations.MajorContents:1.1 Perfect gas equation and mode1.2 Dalton law and Amagat law1.3PVTpropertyof real gas1.4 Van der Waals equation1.5 Liquefaction and critical properties of real gas1.6Principleof corresponding state and diagram of compressibility factorKey Points:1. Perfect gas equation and mode2.DaltonlawandAmagatlaw3. Liquefaction and critical properties of real gas4.Principle of corresponding state and diagram of compressibilityfactorNodus:1. Perfect gas mode and its theoretical explanations2. Liquefaction and critical properties of real gas3.Principle of corresponding statediagram of compressibility factor and relatedcalculationsChapter2TheFirst Lawof Thermodynamics and itsapplications

Syllabus of Zhejiang University of Science and Technology Physical Chemistry (A) Introduction To find out research contents of physical chemistry, understand research approaches and the development trend and characteristics of modern physical chemistry, and master the learning approaches for the course of physical chemistry. Major Contents: 0.1 Research contents of physical chemistry 0.2 Research approaches of physical chemistry 0.3 Establishment and development of physical chemistry 0.4 Development trend and characteristics of modern physical chemistry 0.5 Learning approaches for the course of physical chemistry Key Points: 1. Intentions and contents of physical chemistry 2. Research approaches of physical chemistry 3. Learning approaches for the course of physical chemistry Nodus: 1. Research approaches of physical chemistry 2. Learning approaches for the course of physical chemistry Chapter 1 PVT property of gas To master the perfect gas equation and mode, Dalton law and Amagat law, comprehend the liquefaction and critical properties of real gas, master perfect gas mode and its theoretical explanation, comprehend the principle of corresponding state diagram of compressibility factor and related calculations. Major Contents: 1.1 Perfect gas equation and mode 1.2 Dalton law and Amagat law 1.3 PVT property of real gas 1.4 Van der Waals equation 1.5 Liquefaction and critical properties of real gas 1.6 Principle of corresponding state and diagram of compressibility factor Key Points: 1. Perfect gas equation and mode 2. Dalton law and Amagat law 3. Liquefaction and critical properties of real gas 4. Principle of corresponding state and diagram of compressibility factor Nodus: 1. Perfect gas mode and its theoretical explanations 2. Liquefaction and critical properties of real gas 3. Principle of corresponding state diagram of compressibility factor and related calculations Chapter 2 The First Law of Thermodynamics and its applications

Physical Chemistry (A)Svllabusof ZhejiangUniversityof ScienceandTechnologyTo comprehend the basic conceptions of thermodynamics below:equilibrium state,statefunction,reversibleprocess,etc.,comprehend the description andmathematicalrepresentation of the first law of thermodynamics, master the definitions ofthermodynamic energyenthalpystandard enthalpy of foundation and theirapplications, to master the calculation principlesand methods ofheatwork andvariation of functions in all states when P V T changes,phase changes or during thechemical change process. When applying the general relation of thermodynamics inspecific system, learn to use the state equations (mainly refers toperfect gas equation)and thermodynamic data (heat capacityheat of phase change saturated vaporpressure, etc.).MajorContents:2.1 Thermodynamic conspectus2.2The first law of thermodynamics2.3Quasistatic process and reversibleprocess2.4 Enthalpy2.5Heat capacity2.6 Application of the first law of thermodynamics for perfect gas2.7 Real gas2.8 Thermochemistry2.9 Hesss law2.10 Kirchhoff's law2.11Adiabatic reactionKey Points:1. Basic conceptions of thermodynamics below: equilibrium state, state function,reversible process2. Description and mathematical representation of the first law ofthermodynamics3. Definitions of thermodynamic energy enthalpy standard enthalpy offoundation and their applications4.Master the calculation methods of heatwork and variation of thermodynamicenergy and enthalpy when P V T changes, phase changes or during thechemical changeprocess.Nodus:1.Definitions of thermodynamic energyenthalpystandard enthalpy offoundationandtheirapplications2. Calculation methods of heat work and variation of thermodynamic energy andenthalpy when PVT changes, phase changes or during the chemical changeprocess.Chapter 3The Second Law of ThermodynamicsComprehend the descriptions and mathematical representations of the second and thethird law of thermodynamics. Master the definitions of entropy, Gibbs function,Helmholz function, standard entropy and standard Gibbs function of formation and

Syllabus of Zhejiang University of Science and Technology Physical Chemistry (A) To comprehend the basic conceptions of thermodynamics below: equilibrium state, state function, reversible process, etc., comprehend the description and mathematical representation of the first law of thermodynamics, master the definitions of thermodynamic energy enthalpy standard enthalpy of foundation and their applications, to master the calculation principles and methods of heat work and variation of functions in all states when P V T changes, phase changes or during the chemical change process. When applying the general relation of thermodynamics in specific system, learn to use the state equations (mainly refers to perfect gas equation) and thermodynamic data (heat capacity heat of phase change saturated vapor pressure, etc .). Major Contents: 2.1 Thermodynamic conspectus 2.2 The first law of thermodynamics 2.3 Quasistatic process and reversible process 2.4 Enthalpy 2.5 Heat capacity 2.6 Application of the first law of thermodynamics for perfect gas 2.7 Real gas 2.8 Thermochemistry 2.9 Hess’s law 2.10 Kirchhoff’s law 2.11 Adiabatic reaction Key Points: 1. Basic conceptions of thermodynamics below: equilibrium state, state function, reversible process 2. Description and mathematical representation of the first law of thermodynamics 3. Definitions of thermodynamic energy enthalpy standard enthalpy of foundation and their applications. 4. Master the calculation methods of heat work and variation of thermodynamic energy and enthalpy when P V T changes, phase changes or during the chemical change process. Nodus: 1. Definitions of thermodynamic energy enthalpy standard enthalpy of foundation and their applications. 2. Calculation methods of heat work and variation of thermodynamic energy and enthalpy when P V T changes, phase changes or during the chemical change process. Chapter 3 The Second Law of Thermodynamics Comprehend the descriptions and mathematical representations of the second and the third law of thermodynamics. Master the definitions of entropy, Gibbs function, Helmholz function, standard entropy and standard Gibbs function of formation and

Physical Chemistry (A)Syllabus of Zhejiang University of Science and Technologytheir applications. Master the calculation principles and methods of variation ofentropy, Gibbs function, Helmholz function when P V T changes, phase changes orduring the chemical change process. Comprehend the fundamental equation ofthermodynamics and the derivation of Maxwell relationmastertheapplicabilityofthermodynamic formula and general criterion of the principle of entropy increase andequilibriumMayor Contents:3.1Commonfeaturesofspontaneousvariation3.2Thesecondlawofthermodynamics3.3 Carnot cycle and Carnot theorem3.4 Conception of entropy3.5 Clausius inequality and principle of entropy increase3.6Calculation of entropychange3.7Essence of the second law of thermodynamics and statistic significance ofentropy3.8 Helmholz free energy and Gibbs free energy3.9 Variation direction and equilibrium condition3.10Calculatingdemonstrationof△G3.11 Relation of thermodynamic functions3.12Clapeyron equation3.13 The third law of thermodynamics and conventional entropyKeyPoints1.Description and mathematical representation of the second law ofthermodynamics2. Definitions of entropy, Gibbs function, Helmholz function, standard entropyandstandardGibbsfunctionofformationandtheirapplications3. Calculation principles and methods of variation of entropy, Gibbs function,Helmholz function when P V T changes, phase changes or during the chemicalchangeprocess4. Master the applicability of thermodynamic formula and general criterion of theprinciple of entropy increase and equilibrium.5. Clapeyron equation and Clapeyron-Clausius equation and related calculationsNodus:1. Definitions of entropy, Gibbs function, Helmholz function, standard entropyand standard Gibbs functionofformation and theirapplications.2. Calculation principles and methods of functions in all states when P V Tchanges, phase changes or during the chemical change process3.General criterion of the principle of entropy increase and equilibrium.4.Clapeyron equation and Clapeyron-Clausius equationChapter4Thermodynamicsformulti-componentsystemComprehend the conceptions of partial molar quantity and chemical potential,comprehend Raoult's law and Henry's law and related calculations. Comprehend the

Syllabus of Zhejiang University of Science and Technology Physical Chemistry (A) their applications. Master the calculation principles and methods of variation of entropy, Gibbs function, Helmholz function when P V T changes, phase changes or during the chemical change process. Comprehend the fundamental equation of thermodynamics and the derivation of Maxwell relation master the applicability of thermodynamic formula and general criterion of the principle of entropy increase and equilibrium. Mayor Contents: 3.1 Common features of spontaneous variation 3.2 The second law of thermodynamics 3.3 Carnot cycle and Carnot theorem 3.4 Conception of entropy 3.5 Clausius inequality and principle of entropy increase 3.6 Calculation of entropy change 3.7 Essence of the second law of thermodynamics and statistic significance of entropy 3.8 Helmholz free energy and Gibbs free energy 3.9 Variation direction and equilibrium condition 3.10 Calculating demonstration of ǻG 3.11 Relation of thermodynamic functions 3.12 Clapeyron equation 3.13 The third law of thermodynamics and conventional entropy Key Points: 1. Description and mathematical representation of the second law of thermodynamics 2. Definitions of entropy, Gibbs function, Helmholz function, standard entropy and standard Gibbs function of formation and their applications. 3. Calculation principles and methods of variation of entropy, Gibbs function, Helmholz function when P V T changes, phase changes or during the chemical change process. 4. Master the applicability of thermodynamic formula and general criterion of the principle of entropy increase and equilibrium. 5. Clapeyron equation and Clapeyron-Clausius equation and related calculations Nodus: 1. Definitions of entropy, Gibbs function, Helmholz function, standard entropy and standard Gibbs function of formation and their applications. 2. Calculation principles and methods of functions in all states when P V T changes, phase changes or during the chemical change process. 3. General criterion of the principle of entropy increase and equilibrium. 4. Clapeyron equation and Clapeyron-Clausius equation Chapter 4 Thermodynamics for multi-component system Comprehend the conceptions of partial molar quantity and chemical potential, comprehend Raoult’s law and Henry’s law and related calculations. Comprehend the

Physical Chemistry (A)Syllabus of Zhejiang University of Science and Technologyexpressions of componental chemical potential in ideal system (ideal solution andideal dilute solution). Master the colligative property of dilute solution, comprehendthe conceptions of activity and activity coefficient and simple calculations of activity(fugacity).MayorContents:4.1 Introduction4.2Expression of solution composition4.3 Partial molar quantity and chemical potential4.4Two empirical laws of dilute solution4.5Chemical potential of components in gas mixture4.6 Chemical potential of components in dilute solution4.7Colligative coefficient of dilute solutionKey Points:1. Conceptions of partial molar quantity and chemical potential2. Raoult's law and Henry's law and related calculations3.Expressions of componental chemical potential in ideal system (ideal solutionand ideal dilute solution)4. Colligative coefficient of dilute solutionNodus:1.Conceptions of partial molar quantity and chemical potential2. Raoult's law and Henry's law3. Conceptions of activity and activity coefficient and simple calculations ofactivity (fugacity)4.Expressions of chemical potential of componentsChapter5ChemicalequilibriumMaster the definition of standard constant.Comprehend the derivations of isothermaland isobaric equations in chemical reaction and their applications. Learn to calculateequilibrium constant and equilibrium composition by thermodynamic data. Learn toidentify the possible reaction direction in certain conditions. Learn to analyze theeffects of temperature, pressure, composition, etc. on equilibrium.Mayor Contents:5.1Chemical equilibrium condition and compatible potential5.2 Equilibrium constant and isothermal function of chemical reaction5.3 Relation of equilibrium constant and chemical equation5.4 Heterogeneous chemical equilibrium5.5 Determination of equilibrium constant and calculation of equilibrium rate ofconversion5.6 Standard Gibbs free energy of formation5.7Calculationofequilibriumconstantbypartitionfunction5.8 Effects of temperature, pressure and inert gas on chemical equilibrium5.9 Synchronous equilibriumKey Points:1. Definition of standard constant

Syllabus of Zhejiang University of Science and Technology Physical Chemistry (A) expressions of componental chemical potential in ideal system (ideal solution and ideal dilute solution). Master the colligative property of dilute solution, comprehend the conceptions of activity and activity coefficient and simple calculations of activity (fugacity). Mayor Contents: 4.1 Introduction 4.2 Expression of solution composition 4.3 Partial molar quantity and chemical potential 4.4 Two empirical laws of dilute solution 4.5 Chemical potential of components in gas mixture 4.6 Chemical potential of components in dilute solution 4.7 Colligative coefficient of dilute solution Key Points: 1. Conceptions of partial molar quantity and chemical potential 2. Raoult’s law and Henry’s law and related calculations 3. Expressions of componental chemical potential in ideal system (ideal solution and ideal dilute solution) 4. Colligative coefficient of dilute solution Nodus: 1. Conceptions of partial molar quantity and chemical potential 2. Raoult’s law and Henry’s law 3. Conceptions of activity and activity coefficient and simple calculations of activity (fugacity) 4. Expressions of chemical potential of components Chapter 5 Chemical equilibrium Master the definition of standard constant. Comprehend the derivations of isothermal and isobaric equations in chemical reaction and their applications. Learn to calculate equilibrium constant and equilibrium composition by thermodynamic data. Learn to identify the possible reaction direction in certain conditions. Learn to analyze the effects of temperature, pressure, composition, etc. on equilibrium. Mayor Contents: 5.1 Chemical equilibrium condition and compatible potential 5.2 Equilibrium constant and isothermal function of chemical reaction 5.3 Relation of equilibrium constant and chemical equation 5.4 Heterogeneous chemical equilibrium 5.5 Determination of equilibrium constant and calculation of equilibrium rate of conversion 5.6 Standard Gibbs free energy of formation 5.7 Calculation of equilibrium constant by partition function 5.8 Effects of temperature, pressure and inert gas on chemical equilibrium 5.9 Synchronous equilibrium Key Points: 1. Definition of standard constant

Physical Chemistry (A)Syllabus of Zhejiang University of Science and Technology2.Equilibriumconstantandisothermalfunctionofchemicalreaction3. Calculate equilibrium constant and equilibrium composition by thermodynamicdata4.Identify the possible reaction direction in certain conditions5.Effects oftemperature,pressure, composition, etc.on equilibriumNodus:1.Calculateequilibriumconstantandequilibriumcompositionbythermodynamicdata2. Synchronous equilibrium and related calculationsChapter 6Phase equilibriumComprehend the significance of phase rule and its applications and derivation. Masterthe features and applications of typical phase diagram of single-component and binarysystems. Perform analysis and calculation by lever rule and comprehend the plottingmethod of phasediagram byexperimental dataMayor Contents:6.1 Introduction6.2Phase rule6.3Phase diagram of single component system6.4Phasediagramofbinarysystemand its applicationsKey Points:1.Comprehend the significance of phase rule and its applications2. Features and applications of typical phase diagram of single-component andbinary systems3.Analytical andcalculationmethodsbyleverrule4. Plotting methods of phase diagram by experimental dataNodus:1.Significance of phase rule and its applications2. Features and applications of typical phase diagram of binary systems3.Analytical and calculationmethodsbyleverruleChapter7ElectrochemistryComprehend the physical quantities which represent the electric conductive charactersofelectrolytical solution(electrolyticconductivity,molarconductivity,ionicmobilitytransport number), comprehend the definitions of ionic mean activity and meanactivity coefficient. Comprehend the definition of ionic strength. Comprehend theconception of ionic atmosphere and Debye-Hukel limit formula.Comprehend theconception of reversible cell master Nernst equation and the calculations andapplications of cell electromotive force. Comprehend the conceptions of polarizationand overpotential.Mayor Contents:7.1 Basic conception of electrochemistry and Faraday's law7.2 lonic electromigration and transport number

Syllabus of Zhejiang University of Science and Technology Physical Chemistry (A) 2. Equilibrium constant and isothermal function of chemical reaction 3. Calculate equilibrium constant and equilibrium composition by thermodynamic data 4. Identify the possible reaction direction in certain conditions 5. Effects of temperature, pressure, composition, etc. on equilibrium Nodus: 1. Calculate equilibrium constant and equilibrium composition by thermodynamic data 2. Synchronous equilibrium and related calculations Chapter 6 Phase equilibrium Comprehend the significance of phase rule and its applications and derivation. Master the features and applications of typical phase diagram of single-component and binary systems. Perform analysis and calculation by lever rule and comprehend the plotting method of phase diagram by experimental data. Mayor Contents: 6.1 Introduction 6.2 Phase rule 6.3 Phase diagram of single component system 6.4 Phase diagram of binary system and its applications Key Points: 1. Comprehend the significance of phase rule and its applications 2. Features and applications of typical phase diagram of single-component and binary systems 3. Analytical and calculation methods by lever rule 4. Plotting methods of phase diagram by experimental data Nodus: 1. Significance of phase rule and its applications 2. Features and applications of typical phase diagram of binary systems 3. Analytical and calculation methods by lever rule Chapter 7 Electrochemistry Comprehend the physical quantities which represent the electric conductive characters of electrolytical solution (electrolytic conductivity, molar conductivity, ionic mobility, transport number), comprehend the definitions of ionic mean activity and mean activity coefficient. Comprehend the definition of ionic strength. Comprehend the conception of ionic atmosphere and Debye-Hukel limit formula. Comprehend the conception of reversible cell, master Nernst equation and the calculations and applications of cell electromotive force. Comprehend the conceptions of polarization and overpotential. Mayor Contents: 7.1 Basic conception of electrochemistry and Faraday’s law 7.2 Ionic electromigration and transport number

Physical Chemistry (A)Syllabus of Zhejiang University of Science and Technology7.3Electric conductance7.4 Theoretical introduction of strong electrolytical solution7.5 Reversible cell7.6 Determination of electromotive force7.7 Writing method of reversible cell and sign of electromotive force7.8Thermodynamicsofreversiblecell7.9 The mechanism ofelectromotiveforce production7.10Electrodepotential and cell electromotiveforce7.11 Concentration cell and contact potential7.12 Applications of electromotive force measurement7.13 Electrolyzation and polarizationKey Points:1.Physical quantities which represent the electric conductive characters ofelectrolytical solution2.Conception of reversible cell3. Nernst equation and related calculations4.Calculations and applications ofcell electromotiveforceNodus:1.Definitionsof ionicmeanactivityand meanactivitycoefficient2.Polarization and conception ofoverpotential3.Concentrationcell and related calculationsChapter 8Basic statistic thermodynamicsComprehend the basic hypothesis of statistic thermodynamics and the significanceandapplicationsofBoltzmanndistribution.Master thesignificanceofpartitionfunction and the relations of partition function and thermodynamic functionMayor Contents:8.1Introduction8.2 Boltzmann statistic8.3 Partition function8.4 Calculations of partition functions8.5 Contributions of partition functions to thermodynamic function8.6Calculations of monatomic perfect gas thermodynamic functionsKey Points:1. Basic hypothesis of statistic thermodynamics2.SignificanceandapplicationsofBoltzmanndistribution3. Significance of partition function4. Relations of partition function and thermodynamic functionNodus:1. Significance and applications of Boltzmann distribution2.Calculations of partition function3. Relations of partition function and thermodynamic function and relatedcalculations

Syllabus of Zhejiang University of Science and Technology Physical Chemistry (A) 7.3 Electric conductance 7.4 Theoretical introduction of strong electrolytical solution 7.5 Reversible cell 7.6 Determination of electromotive force 7.7 Writing method of reversible cell and sign of electromotive force 7.8 Thermodynamics of reversible cell 7.9 The mechanism of electromotive force production 7.10 Electrode potential and cell electromotive force 7.11 Concentration cell and contact potential 7.12 Applications of electromotive force measurement 7.13 Electrolyzation and polarization Key Points: 1. Physical quantities which represent the electric conductive characters of electrolytical solution 2. Conception of reversible cell 3. Nernst equation and related calculations 4. Calculations and applications of cell electromotive force Nodus: 1. Definitions of ionic mean activity and mean activity coefficient 2. Polarization and conception of overpotential 3. Concentration cell and related calculations Chapter 8 Basic statistic thermodynamics Comprehend the basic hypothesis of statistic thermodynamics and the significance and applications of Boltzmann distribution. Master the significance of partition function and the relations of partition function and thermodynamic function Mayor Contents: 8.1 Introduction 8.2 Boltzmann statistic 8.3 Partition function 8.4 Calculations of partition functions 8.5 Contributions of partition functions to thermodynamic function 8.6 Calculations of monatomic perfect gas thermodynamic functions Key Points: 1. Basic hypothesis of statistic thermodynamics 2. Significance and applications of Boltzmann distribution 3. Significance of partition function 4. Relations of partition function and thermodynamic function Nodus: 1. Significance and applications of Boltzmann distribution 2. Calculations of partition function 3. Relations of partition function and thermodynamic function and related calculations

Physical Chemistry (A)Syllabus of Zhejiang University of Science and TechnologyChapter99InterfacialphenomenonComprehend the conceptions of surface tension and surface Gibbs function and therelationsofcontactanglewettingand spreading.Comprehendtheeffectsof flexuralliquid lever on thermodynamic properties and Laplace formula and the applications ofKelvinformula.Comprehend therelations of metastable stateand new phaseproduction. Comprehend the adsorption of solution interface and the effects ofsurfactant.ComprehendthesignificanceandapplicationsofGibbs adsorptionformula.Comprehend the significance and differences of physisorption and chemisorption.Comprehend Langmuir monolayer adsorption theory and adsorption isothermalformula.Maincontents9.1SurfaceGibbsfreeenergyand surfacetension9.2 Additional pressure and vapor pressure of flexural liquid lever9.3 Properties of liquid interface9.4 Liquid-solid interfacial phenomenon9.5 Adsorption of solid surface9.6Surfactant and its effectsKey Points:1. Conceptions of surface tension and surface Gibbs function and the relations ofcontact anglewettingandspreading2.Effects of flexural liquid lever on thermodynamic properties and Laplaceformula and the applications of Kelvin formula3. Adsorption of solution interface4. Langmuir monolayer adsorption theory and isothermal formulaNodus:1.Effects of flexural liquid lever on thermodynamic properties and Laplaceformula and the applications of Kelvin formula2. Relations ofmetastable state and new phase production3. Langmuir monolayer adsorption theory and isothermal formula and multilayeradsorption theoryChapter 10Basic chemical kineticsComprehend the conceptions of chemical reaction rate, reaction rate constant andreaction order. Master the methods to establish rate equations by experiments and therate equations of first order and second order reactions and their applications.Comprehend the characters of typical complexreactions.Comprehendthe kineticmethodsdealingwithopposingreaction,parallelreactionandconsecutivereactionComprehend the conceptions of elementary reaction and molecularity of reaction.Comprehend the conceptions of steady state approximation,equilibriumapproximation and control process and the kinetic features of chain reaction.Mayor Contents:10.1Assignmentandpurposeofchemicalkinetics10.2Expressionofchemicalreactionrate10.3 Rate equation of chemical reaction

Syllabus of Zhejiang University of Science and Technology Physical Chemistry (A) Chapter 9 Interfacial phenomenon Comprehend the conceptions of surface tension and surface Gibbs function and the relations of contact angle wetting and spreading. Comprehend the effects of flexural liquid lever on thermodynamic properties and Laplace formula and the applications of Kelvin formula. Comprehend the relations of metastable state and new phase production. Comprehend the adsorption of solution interface and the effects of surfactant. Comprehend the significance and applications of Gibbs adsorption formula. Comprehend the significance and differences of physisorption and chemisorption. Comprehend Langmuir monolayer adsorption theory and adsorption isothermal formula. Main contents: 9.1 Surface Gibbs free energy and surface tension 9.2 Additional pressure and vapor pressure of flexural liquid lever 9.3 Properties of liquid interface 9.4 Liquid-solid interfacial phenomenon 9.5 Adsorption of solid surface 9.6 Surfactant and its effects Key Points: 1. Conceptions of surface tension and surface Gibbs function and the relations of contact angle wetting and spreading 2. Effects of flexural liquid lever on thermodynamic properties and Laplace formula and the applications of Kelvin formula 3. Adsorption of solution interface 4. Langmuir monolayer adsorption theory and isothermal formula Nodus: 1. Effects of flexural liquid lever on thermodynamic properties and Laplace formula and the applications of Kelvin formula 2. Relations of metastable state and new phase production 3. Langmuir monolayer adsorption theory and isothermal formula and multilayer adsorption theory Chapter 10 Basic chemical kinetics Comprehend the conceptions of chemical reaction rate, reaction rate constant and reaction order. Master the methods to establish rate equations by experiments and the rate equations of first order and second order reactions and their applications. Comprehend the characters of typical complex reactions. Comprehend the kinetic methods dealing with opposing reaction, parallel reaction and consecutive reaction. Comprehend the conceptions of elementary reaction and molecularity of reaction. Comprehend the conceptions of steady state approximation, equilibrium approximation and control process and the kinetic features of chain reaction. Mayor Contents: 10.1 Assignment and purpose of chemical kinetics 10.2 Expression of chemical reaction rate 10.3 Rate equation of chemical reaction

Physical Chemistry (A)Syllabus of Zhejiang University of Science and Technology10.4Reactionswithsimpleorders10.5 Some typical complex reactions10.6 Effects of temperature on reaction rate10.7Effects ofactivation energyonreactionrate10.8Chainreaction10.9GeneralmethodstodraftreactionmechanismKey Points:1.Conceptions of chemicalreactionrate,reactionrateconstantandreaction order2.Rateequationsof firstorder and second order reactions and theirapplications3. Characters of typical complex reactions., comprehend the kinetic methodsdealing with opposing reaction, parallel reaction and consecutive reaction.4. Significance of Arrhenius equation and its applicationsNodus:1. Methods to establish rate equations by experiments2. Conceptions of steady state approximation, equilibrium approximation andcontrolprocessandtheirapplications3. Features of complex reactions and related calculationsChapter11Dynamics of special reactionComprehend the necessary process of multi phase reaction.Comprehend catalysis andthedefinitions of activation energy and pre-exponential factor.Comprehend the basictheory of elementary reaction rate.Comprehend the basic formulas of effectivecollision theory and transition state theory and related conceptions.Mayor Contents:11.1 Collision theory11.2 Transition state theory11.3 Unimolecular reaction theory11.4Photochemistry reaction11.5CatalyticreactionkineticsKey Points:1. Basic theory of elementary reaction rate2. Basic formulas of effective collision theory and transition state theory andrelated conceptions.3. Necessary process of multi phase reaction4.Catalytic reaction kineticsNodus:1.Basic theory of elementary reaction rate2. Basic formulas of effective collision theory and transition state theory andrelated conceptions.Chapter 12CollochemistryComprehend the classification of disperse system and the definition of colloid

Syllabus of Zhejiang University of Science and Technology Physical Chemistry (A) 10.4 Reactions with simple orders 10.5 Some typical complex reactions 10.6 Effects of temperature on reaction rate 10.7 Effects of activation energy on reaction rate 10.8 Chain reaction 10.9 General methods to draft reaction mechanism Key Points: 1. Conceptions of chemical reaction rate, reaction rate constant and reaction order 2. Rate equations of first order and second order reactions and their applications 3. Characters of typical complex reactions., comprehend the kinetic methods dealing with opposing reaction, parallel reaction and consecutive reaction. 4. Significance of Arrhenius equation and its applications Nodus: 1. Methods to establish rate equations by experiments 2. Conceptions of steady state approximation, equilibrium approximation and control process and their applications 3. Features of complex reactions and related calculations Chapter 11 Dynamics of special reaction Comprehend the necessary process of multi phase reaction. Comprehend catalysis and the definitions of activation energy and pre-exponential factor. Comprehend the basic theory of elementary reaction rate. Comprehend the basic formulas of effective collision theory and transition state theory and related conceptions. Mayor Contents: 11.1 Collision theory 11.2 Transition state theory 11.3 Unimolecular reaction theory 11.4 Photochemistry reaction 11.5 Catalytic reaction kinetics Key Points: 1. Basic theory of elementary reaction rate 2. Basic formulas of effective collision theory and transition state theory and related conceptions. 3. Necessary process of multi phase reaction 4. Catalytic reaction kinetics Nodus: 1. Basic theory of elementary reaction rate 2. Basic formulas of effective collision theory and transition state theory and related conceptions. Chapter 12 Collochemistry Comprehend the classification of disperse system and the definition of colloid

Physical Chemistry (A)Syllabus of Zhejiang University of Science and TechnologyComprehend the reasons for colloid stabilization and destruction. Comprehend theclassificationand stabilization of emulsionMayor Contents:12.1Preparation of colloid system12.2Optical properties ofcolloid system12.3 Dynamic properties of colloid system12.4 Electrical properties of colloidal sol system12.5Stabilizationandcoagulationofcolloidalsol12.6 Suspension and emulsion:Key Points:1. Classification of disperse system and definition of colloid2. Optical and dynamic properties of colloid system3.Classification and stabilization ofemulsionNodus:1.Optical and dynamic properties of colloid system2.Electrical properties of colloidal sol systemThe distribution of experimental hours: total 102. The distribution is listed asbelow:SNTeaching contentsHours14Gas212 The first law of thermodynamics312 The second law of thermodynamics48Thermodynamics of multi-component system58Chemical equilibrium86Phase equilibrium712Electrochemistry88Statistic thermodynamics98Interfacial phenomenon1210Chemical kinetics114Dynamics of special reaction126CollochemistryD.Arrangement and Examination Methods for Teaching Segmenta. Classroom Lecturing(1). Lecturing: Systematical lecturing shall be carried out for the part of basictheory of this course

Syllabus of Zhejiang University of Science and Technology Physical Chemistry (A) Comprehend the reasons for colloid stabilization and destruction. Comprehend the classification and stabilization of emulsion. Mayor Contents: 12.1 Preparation of colloid system 12.2 Optical properties of colloid system 12.3 Dynamic properties of colloid system 12.4 Electrical properties of colloidal sol system 12.5 Stabilization and coagulation of colloidal sol 12.6 Suspension and emulsion: Key Points: 1. Classification of disperse system and definition of colloid 2. Optical and dynamic properties of colloid system 3. Classification and stabilization of emulsion Nodus: 1. Optical and dynamic properties of colloid system 2. Electrical properties of colloidal sol system The distribution of experimental hours: total 102. The distribution is listed as below: SN Teaching contents Hours 1 Gas 4 2 The first law of thermodynamics 12 3 The second law of thermodynamics 12 4 Thermodynamics of multi-component system 8 5 Chemical equilibrium 8 6 Phase equilibrium 8 7 Electrochemistry 12 8 Statistic thermodynamics 8 9 Interfacial phenomenon 8 10 Chemical kinetics 12 11 Dynamics of special reaction 4 12 Collochemistry 6 D. Arrangement and Examination Methods for Teaching Segment a. Classroom Lecturing (1). Lecturing: Systematical lecturing shall be carried out for the part of basic theory of this course