北京化工大学：《化学反应工程》课程PPT教学课件（英文版）Chemical reaction engineering（2011）Chapter 11-15

Chapter 11 Basics of Non-Ideal Flow So far we have treated two flow patterns,plug flow and mixed flow.Most cases we try to design equipment to approach one or the other.But real equipment always deviates from these ideals. In this chapter,we deals with: RTD state of aggregation earliness and lateness of mixing 1

1 Chapter 11 Basics of Non-Ideal Flow So far we have treated two flow patterns, plug flow and mixed flow. Most cases we try to design equipment to approach one or the other. But real equipment always deviates from these ideals. In this chapter, we deals with: RTD state of aggregation earliness and lateness of mixing

The Residence Time Short-circuiting- Distribution,RTD ·To simplify,.we will only consider Stagnant regions the steady-state flow, Packed bed without reaction and without density Channeling,especially Extreme short-circuiting and bypass serious in countercurrent two-phase operations change,of a single fuid through a vesse Nonidealatems which mayin roce equipment. 2

2 The Residence Time Distribution, RTD • To simplify, we will only consider the steady-state flow, without reaction and without density change, of a single fluid through a vessel

State of Aggregation of the Flowing Stream Microfluids and Macrofluids Gases and ordinary Noncoalescing droplets not very viscous Solid particles liquids Very viscous liquids Microfluid Macrofluid Molecules are kept Individual molecules are free grouped together in to move about and intermix aggregates or packets Figure 11.2 Two extremes of aggregation of fluid. 3

3 • State of Aggregation of the Flowing Stream • Microfluids and Macrofluids

Single-Phase Systems These lie somewhere between the extremes of macro-and microfluids. ·Two-Phase Systems A stream of solids always behaves as a macrofluid,but for gas reacting with liquid, either phase can be a macro-or microfluid depending on the contacting scheme being used. 4

4 • Single-Phase Systems • These lie somewhere between the extremes of macro- and microfluids. • Two-Phase Systems • A stream of solids always behaves as a macrofluid, but for gas reacting with liquid, either phase can be a macro- or microfluid depending on the contacting scheme being used

Spray tower Sparger reactor reactor L G G Gas bubbles Liquid droplets in liquid in gas G -Here gas is a macrofluid while liquid is a microfluid -Here gas is a microfluid while liquid is a macrofluid Figure 11.3 Examples of macro-and microfluid behavior. 5

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。Earliness of Mixing the fluid elements of a single flowing stream can mix with each other either early or late in their flow through the vessel Early mixing Uniform mixing Late mixing 00 00 Lots of mixing Flat- Same along LNo mixing Well-mixed of young and velocity the whole of young and region old fluid profile vessel old fluid Figure 11.4 Examples of early and of late mixing of fluid. 6

6 • Earliness of Mixing • the fluid elements of a single flowing stream can mix with each other either early or late in their flow through the vessel

For a system with two entering reactant streams,earliness or lateness of mixing can be very important. A 60 B LWell mixed at entry, Separate parallel LMixing only occurs so A and B have flows so A and B at exit leaving no lots of time for reaction are unable to react time for reaction Figure 11.5 Early or late mixing affects reactor behavior. 7

7 • For a system with two entering reactant streams, earliness or lateness of mixing can be very important

Role of RTD,State of Aggregation,and Earliness of Mixing in Determining Reactor Behavior In some situations one of these three factors can be ignored,in others it can become crucial.Often,much depends on the time for reaction t,the time for mixingtmix,and the time for stay in the vessel tsty.In many casests has a meaning somewhat like but somewhat broader. 8

8 • Role of RTD, State of Aggregation, and Earliness of Mixing in Determining Reactor Behavior • In some situations one of these three factors can be ignored, in others it can become crucial. Often, much depends on the time for reaction , the time for mixing , and the time for stay in the vessel . In many cases has a meaning somewhat like but somewhat broader. trx t mix t stay t stay t mix

11.1 E,The Age Distribution of Fluid,the RTD In this section,we do not consider any reaction It is evident that elements of fluid taking different routs through the reactor may take different lengths of time to pass through the vessel.The distribution of these times for the stream of fluid leaving the vessel is called the exit age distribution E,or the residence time distribution RTD of the fluid. E has the units of time-1. 9

9 11.1 E, The Age Distribution of Fluid, the RTD • It is evident that elements of fluid taking different routs through the reactor may take different lengths of time to pass through the vessel. The distribution of these times for the stream of fluid leaving the vessel is called the exit age distribution E, or the residence time distribution RTD of the fluid. E has the units of time -1 . In this section, we do not consider any reaction

As a beginning,we have a review of ideal flow reactor MFR (CSTR)in which fluid has maximum back-mixing PFR in which there isn't any back-mixing Non-ideal reactor:it's back-mixing between CSTR and PFR back-mixing The mix of fluid with different stay time 10

10 • As a beginning, we have a review of ideal flow reactor • MFR（CSTR） in which fluid has maximum back-mixing • PFR in which there isn’t any back-mixing • Non-ideal reactor: it’s back-mixing between CSTR and PFR • back-mixing The mix of fluid with different stay time