《有机化学》课程教学资源_试题库_题库二_试题库2-3：完成反应式答案

试题库三：完成反应式答案 LCHCCHCH 2.CHOCHCH 3出”提龄 4.CH3CH2CH2OH 5.(CH3)2C=O+CH:CH2CHO 6.Clz+H2O 7.CH3CH2CH2CCl2CH 8.CH3CH2CH2CBr2CH3 9.CH3CH2COOH+CH3COOH actagaah+aaoga 11.o 2○ a 4a合a 16. CHa ICH-CCHCHCHCHCHO 18.aco 19.△co0i a○8的 2100a CO 2 C 24.0 0l 25.HOOC 6Og8 0 27.CoHsCH-MgCl C.CH.C OMCI C.H.CH.COOH 28.CH2=CHCHzOC2Hs 30.O8rC①ao CH2CH 31. 34." OH 35.0 36. A

1 试题库三：完成反应式答案 2． 4．CH3CH2CH2OH 5．(CH3)2C=O + CH3CH2CHO 6． Cl2+H2O 7．CH3CH2CH2CCl2CH3 8．CH3CH2CH2CBr2CH3 9．CH3CH2COOH + CH3COOH 19． 24． 34． 36． (CH3 )2C-CH2CH3 Br 1. CH3OCHCH3 Br H2O2 B2H6 H HBr 2O2 H2O OH - OH 3. - 或 CH3CH2CCH2CH3 + CH3CH2CH2CCH3 O O 10. CHO 11. CH3 12. Br Cl 13. CH2CH3 CH2CH3 Br Br 15. + C(CH3 )2 16. Cl Cl Cl 14. CH3 -C-CH2CH2CH2CH2CHO O 17. 18. CH3 CHO COOH CH3 20. OH H2 C CH2Cl 21. 或 CH3 NO2 22. SO3H Br 23. CH3 SO3H 25. HOOC CH-CH 2 Cl Cl 26. C6H5CH2MgCl C6H5CH2C OMgCl O 27. C6H5CH2COOH 28. CH2=CHCH2OC2H5 CH=CHBr CH2ONO2 29. Br Br CHO 30. CH2OH Cl 31. OH CH3 32. CH3 + OH CH3 33. HO CH3 35. 乙醇 NaCN , △

37.(CH3)C-OH 38.(CH3)2CHCH2CH2Br 9.○-a 0.0 41.atca 42.9,a,a,a9a 43.(CH2CH.0-C2H 4.OC0 45.CHaCH2CH-CCH3 “的 OHO 48.CH3CH2CH=CHCH2CH3 N-OH 51.HOOC-COOH 49.CH2CCH2CHs 52.CH3CHz-CH-CHCHO 50.ClsCCH(OH)2 OH CH3 OMgBr OH 53.CHCCoHs CoHs-CC.Hs 54.NNHCoHs CHO 56.(CH3)sCCOOH o 58.HOOCCH2CH2CH2COOH 59.○c00mH 60.●co0°+aH0; 61.O8cH8 62.CH3CH(CI)CH2CH2COCH3 64.CH,COCHCOOH 63.C6HsCH(OH)CH2COCH3 “或 HCH.CHC 66 CHOH -CH 67.○c0cH, 68.CHCOCHH 6.CHCHCHCOON 70.CH3CH=CHCOOH OH

2 37．(CH3)3C-OH 38．(CH3)2CHCH2CH2Br 40． 43．(CH3)2CH- O-C2H5 48．CH3CH2CH=CHCH2CH3 50．Cl3CCH(OH)2 56 ． (CH3)3CCOOH + (CH3)3CCH2OH 58．HOOCCH2CH2CH2COOH 62． CH3CH(Cl)CH2CH2COCH3 63．C6H5CH(OH)CH2COCH3 39. Cl I CH2CH2 I 41. CH2CH2CH2CH2CHCH 3 I I 42. CH3CH2CH2CH2CCH3 O 44. CH3CH2CH-CCH 3 OHO 45. CH3 OH OH 46. CH3 OH Br Br 47. CH2CCH2CH3 N OH 49. 51. HOOC COOH CH3CH2 -CH-CHCHO OH CH3 52. C6H5 -C-C6H5 OMgBr CH3 53. C6H5 -C-C6H5 OH CH3 NNHC6H5 54. C CH3 CH3 O O C H2 H2 C 57. 55. N-OH 59. COOH CHCl COO 3 - 60. + CCH2Cl O 61. CH3COCHCOOH CH3 64. H2C H2C C C O O O 65. H3CH2CHC O C C O O O CHCH 2CH3 66. 67 COCH3 . CH3COCH CH3 CH3 68. CH3CH2CHCOONa OH 69. 70. CH3CH=CHCOOH

CH3 71.CH2CHCH2COONa OH 74.CH3CHCHO+CO2 73.CHgCH2CHO CO2 CH3 0Cm 77.CHCHCOOH 0 79.HCCOOCHMe 2 80.HOCH2CH2CH2OH 81.NaOOCCH:CH:COONa HOOCCH:CHCOOH 200 84.-OCOCH3 86.CH3COOCH2CH2CH3+CH3CH2OH 87.CH3CH2COOH CO2 89.-cooc:cg00c 90. CHOH 91.○oocH 26 9g.o0+ 94.[(C2Hs)NCHMe2]Br 95.[(CHs)sNCH2CH2CH2CHs]*+Na*+ CF+OH N(CzHs)z 97. NO CH.CH, OH CH2-C=0 c 103.CHCHCH-CCHO 105083 3

3 80．HOCH2CH2CH2OH 81．NaOOCCH2CH2COONa HOOCCH2CH2COOH 86．CH3COOCH2CH2CH3 + CH3CH2OH 87．CH3CH2COOH + CO2 88． 89． 90． 91． 92． 93． 94．[(C2H5)3NCHMe2] +Br- 95．[(CH3)3NCH2CH2CH2CH3] ++Na++ Cl-+OH- 96． 97． 103． 104． CH2CHCH2COONa OH CH3 71. CH3CH2C=O CH3 72. + HCOOH 73. CH3CH2CHO + CO2 C C O O O 75. CH3CHCHO + CO2 CH3 74. CH2CH2COONa OH 76. CH3CHCOOH Cl 77. COOH COOH 78. COOCHMe 2 79. H3C 82. O CH3 COCH3 83. OCOCH3 84. CH3CH2CCHCOOEt CH3 O 85. COOH Cl COOCH2CH2OOC CH2OH OOCH O COOEt N COO - + NH3 H3C N CCH2CH3 CH3 O N(C2H5 )2 NO CH3SCH3 O 100. O COOC2H5 O COOC2H5 O CH2CH3 O C2H5OOC O HOOC Na + - CH2CH3 CH2CH3 98. CH2CH2CH2COOH OH CH2 CH2 C CH2 O O 99. O H COONa 3C O H3C CH2OH 101. N COOH COOH 102. CH3CH2CH=CCHO CH3 CH3CH2CH=CCH 2OH OH CH3 CN OH COOH S S 105

106.CH3CH2MgBr CH CH CHCH,CH CH2CHCH; 107.CoHsCH-C-CHO OH 00 CH2CH3 108.HSCH-CHOH w0C8Cg8 110.CH,CH,CH,CH=N-○ 111.(CH3)CHCHCOOH eC 113.OCs 4.Q s◇X8 116.-CH-CH2 17aaunarm SO Na 118.-COCH 119.CH-NH2 120. 1.O 122.CH=CHCOCH 133.0 124.Br-CH3 125.○000m 126.NHCOCH CH, 127.CH;(CH2)4NH2 128.CHC-NNHCONH 129.CICH-CH2 CH3 0 130. 13L. CH 133. CONH:NI. CH=NNHph 134 135.CH,CH2MgCI CH CH-COOH CH,CH-COCI 136. H,C-《-NHCOCH 137.(CH3)CHC-CH2 NO2 138. 139.○Qo 140.CH;(CH2)4CONH2 CH:(CH2)4NH2

4 109． 113． 114． 127． 129． 134． 135． 136． 137． 138． 139． 140． CH3CH2MgBr CH3CH2CHCH 3 OH CH3CH2CHCH 3 O O CH2 -CH2 106. C6H5CH=C-CHO CH2CH3 107. 108. HSCH2CH2OH OH OH O O C CH3 CH3 110. CH3CH2CH2CH N (CH3 )2CHCHCOOH Br 111. COOH COOH 112. O O2N CH3 NH OH CN 115. 116 CH=CH2 . CH3CH2CH2CH SO3Na OH 117. CH3CH2CH2CHO 118. COOH 119 CH2NH2 . O CH3 NO2 120. CH3CH OCH3 OCH3 121. 122. CH2=CHCOCH3 N COOH 123. B CH3 124. r COOH 125. 126. NHCOCH 2CH3 CH3 (CH2 )4NH2 C6H5C=NNHCONH 2 CH3 128. ClCH=CH 2 N COCl N CH3 C O 130. CHC CHC O O 131. O N H CH3 NO2 132. Cl CONH2 Cl 133. NH2 CH CH2OH NNHph NNHph C6H5CH2MgCl C6H5CH2COOH C6H5CH2COCl H3C NHCOCH 3 NO2 (CH3 )2CHC=CH 2 S O COCH3 2N O CH3 (CH2 )4CONH2 CH3 (CH2 )4NH2

CH-CN 142.H0,-G0,N-③ 146. 147.clco eOga CLLC 149. 1500o 151.0 coa 152.phCH:CH-CH2 8>西 900H 153. CH.SH 154 155. 156C8a,a0 158.CHCH-CH.CH SO,H NO.C3 . 165.○N CH3 166.CNCN CH 167.HCH HCI 686 169aagg2 170.CH3CH2I (CH3)2CHI 5

5 CH2Cl C CH2Cl HO CN CH2Cl C CH2Cl HO COOH CH2CN C CH2CN HO COOH CH2COOH C CH2COOH 141. HO COOH H CH3 SO2 N CH3 SO2 N Na + - 142. COOH NO2 143. NH2 OCOCH 3 146. COOH 144. CF3 NO2 145. 147. CHCOOH CH2C CH2C O O O CCH2CH2COOH O CH2CH2CH2COOH CH2CH2CH2COCl O 148. N2 Cl + - OH 149. N=N COOH HO 150. COCl 151. 152. phCH2CH=CH 2 CH2S CHS CH2SH Hg 153. COOH N 154. CH NNHCNH 2 O 155. CHCH 2CHO OH 156. O OH CH3 CH3 CH3 OH CH3 157. 158. CH3CH2CH2CH2SO3H O2N NHN=CCH 2CH3 NO2 CH3 159. HOCH2CH2CH OH CN O O OH 160. COOH COOH COOH COOH C C C C O O O O O O 161. CH3 NHCOCH3 HNO3 H2SO4 CH3 NHCOCH3 NO2 CH3 NH2 NO2 CH3 NH2 162. CH3C=CHCH3 CH3 H3C C H3C O O O CHCH3 CH3 -C-CH3 O 163. CH3CHO CF3 F F F 164. H-C-H O 167 HCl . CN 165. CN CH3 CN CH3 166. + CH2Cl CH2Cl Cl CH2Cl Cl CH2OH Cl CH2OH Cl 168. CH3CH2CH-C-CH 3 CH3O 169. CH3CH2 I (CH3 ) 170. 2CHI

m.om 172rCHMgBrCH CH.CsCMe mC 14.◇HCHCH Br 175.CHsCHO HCOOH CHs-CCH3 176.CH;CH2C=CNa:CHsCH2C=C CHs: 29成烯 177.CHC=CNa =c 179.CHCH-CHOH CH-OH:CHCH-CHO+HCHO 181. 180.O O e08e 10 184.○oH+aH,0H H 185.○on+ca 000 0 18.Q 189. 190.CHsCHICH:CHs 191.CICH-CH-CH-CI 192.CH:CH-CH: CHO 16○8 197.○-cH,0m 198.CHCOOH+HOOCH:CH-COOH 19.白 201. 如克克 203.OHC(CH2)4CHO

6 176．CH3CH2C≡CNa；CH3CH2C≡C CH3；反 -2-戊烯 179． CH3CH2CHOH CH2OH；CH3CH2CHO+HCHO 185． 189． 190．CH3CHICH2CH3 191．ClCH2CH2CH2Cl 192．CH3CH2CH3 193 ． CH3CHBrCH2CH3 197． 198．CH3COOH + HOOCH2CH2COOH CH3 171. COOH 172 CH2Br CH2MgBr CH3 CH3C≡CMgBr . CH OH Br 173. CH-CH 2CH3 Br 174. CH3CHO HCOOH CH3 -C-CH3 O 175. + + CH3C≡CNa CH3C≡CCH 2CH3 C CH3 C H CH2CH3 H 177. C CH3 C H CH3 H 178. 180. CH=CHCN CH2Cl 182. C O 181. OH CH3 + CH3CH2 184 I . CH=CHOC 2H5 Cl 183. OH + CH3 I O O O O 186. O O O 187. O O O 188. O O O CH2CH2CHCH2CHO CHO 195. CH3 OH 196. (CH3 )2C- C-CH 3 Br CH3 194. CH2OH Br CH2O 199. MgBr Cl 200. OH Cl MgBr Cl 201. Br CH2MgBr Br CH3 202. OHC(CH 2 ) 203. 4CHO

CH,COCH 205.CH2=CHCH3 “氏·且 207.HCHCH 208.HoOC-CM 6, NO 210.☐CNON 21.⊙8ow 2."省"名 21. 215. OCHH 216.Me2CCH CI 217 218.CCCCHCCOOH 219. 0 220 PhCHCHCH3 PhCH=CHCHs PhCH-CHCHs PhCOOH CHCOOH CI CICI % 221 222 223 224. 8ew 225 26. 227 OJN 228. a3"00oH 229. 230.CH3CHCH-CH 231. agat+oaoto 232. 233.0

7 205． 208． 209． 210． 211． 212． 213． 214． 215． 216． 217． 218． 219． 220． 221． 222． 223． 224． 225． 226． 227． 228． 229． 230． 231． 232． 233． C-OOH AlCl3 H3C CH3 HO CH3COCH3 204. CH3 Br CH3 Br + CH3 Br CH3 206 Br . CH2CHCH2CH≡CH Br Br 207. CH2=CHCH3 HOOC CMe3 CH3 NO2 CH3 NO2 + CH2CH2CH2CH3 CH-CH2Br Br H Br 3C H MgBr 3C H3C D D CH2Br D CH2MgBr Cl Cl Cl COOEt CH2CH2CH2CH2 Br Br Me2CCH3 Cl Me2CCH3 Cl CHCH2CH3 CH=CHCH3 COOH Br C C O O O PhCHCH2CH3 Cl PhCH=CHCH3 PhCH-CHCH3 Cl Cl PhCOOH + CH3COOH CH3 B 3 CH3 OH CH3 OCH3 CH(CH3 )2 Me2CH CMe3 CH3 OH + C2H5 I CH3CH2CCH 2Br O CH3CHCH2 OH CN SO3H SO3H C CH3CH2 C H CH2CH3 H CH3CHCH=CH2 Cl CH3CCH3 O + OHCCHO+ HCHO CH3 Br Br

234.CH2=CHCN 235.a9a0 236. 237.HCN CH.CHCN 258.a6da8H .子 OH 240 241. 人M人入 22.a60,a 243.0 244. 245. 246 NO-No. 27.01, CH 248.cc-cc

8 234． 235． 236． 237． 238． 239． 240． 241． 242． 243． 244． 245． 246． 247． 248． CH2 =CHCN CH3CHCH2CH3 Br CH3CHCH3 Br HCN CH3CH2CN (CH3 )2CHMgBr (CH3 )2CHCH3 OMgBr OH NO2 O2N NO2 OH NO2 Cl MgBr OH CH3C= C-CH 2CH3 CH3 CH3 CH3 OH Br Br CH3 Cl CH3 Cl CH2Cl Cl CH2Cl Cl CH2COOH Cl CH2COOH Cl CH3 NO2 NO2 CH3CH=C-CH 3 CH3 CH3 -C-CH 2CH3 Br CH3